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Category: Thermodynamics

Open, Closed & Isolated Systems

February 19, 2015November 29, 2021 Surfguppy17 CommentsThermodynamics

Teach AP® chemistry with confidence and ease Open, Closed & Isolated Systems A system refers to any parts of the universe being studied. If you are conducting an experiment in a beaker, then the system you are studying is in Read More …

System and Surroundings

January 22, 2015January 28, 2021 Surfguppy2 CommentsThermodynamics

Enthalpy Change Calculation

November 8, 2014January 28, 2021 Surfguppy1 CommentThermodynamics
Propane combustion

Propane Combustion When 0.5 g of propane is burned, the heat produced is used to raise the temperature of 100 cm³ of water from 20ºC to 40ºC. Calculate the enthalpy change (ΔH) for the reaction. Given the density of water Read More …

calculations

Enthalpy, Entropy & Gibbs Free Energy

November 8, 2014November 30, 2020 Surfguppy1 CommentThermodynamics
icon-gibbs-free-energy

 Enthalpy  Entropy Gibbs Free Energy       Enthalpy is the amount of heat energy transferred (heat absorbed or emitted) in a chemical process under constant pressure. Entropy measures the amount of heat dispersed or transferred during a chemical process. Gibbs Read More …

Enthalpy

November 8, 2014January 28, 2021 SurfguppyLeave a commentThermodynamics
delta H

The term enthalpy change is a term to describe the amount of heat that passes in or out of a system during a chemical reaction under constant pressure. Calorimeter In school, you can measure the heat exchange of a reaction Read More …

Reaction Spontaneity

May 10, 2014January 29, 2021 SurfguppyLeave a commentThermodynamics

(Picture above – dog escaping over the fence – winter 2015) A spontaneous process A spontaneous process is a physical or chemical change that occurs with no outside intervention. In life, many things happen spontaneously. For example, my dog escaped Read More …

Hess’s Law

May 9, 2014January 28, 2021 SurfguppyLeave a commentThermodynamics
cow

Hess’s law states that energy change in the overall chemical reaction is the sum of energy change or enthalpy change in the individual reactions that comprises it. Hess’s Law states that the heat evolved or absorbed in a chemical process is Read More …

Hess Law – Calculation for Methane Formation

May 9, 2014January 28, 2021 SurfguppyLeave a commentThermodynamics
Calculation for Methane formation using Hess Law - Chemistry

Methane gas – CH₄ What is the enthalpy change when methane is formed using carbon graphite and hydrogen? When a chemical reaction takes place, heat is either given off or absorbed. If heat is given off, it is called an Read More …

Understanding Gibbs Free Energy

May 9, 2014August 19, 2021 Surfguppy5 CommentsThermodynamics

What is Gibbs Free Energy? For a simple definition, Gibbs free energy can be described as the amount of energy available to do work. Gibbs Free Energy is invented by Josiah Willard Gibbs (February 11, 1839 – April 28, 1903) Read More …

Gibb’s Free Energy – Ammonia

May 8, 2014December 1, 2020 SurfguppyLeave a commentThermodynamics

The Haber process to manufacture ammonia using nitrogen and hydrogen is given by the equation below: Calculate Gibb’s free energy change (ΔG) at 298 K temperature. Given the entropy change (ΔS): -198 J K⁻¹ mol⁻¹ Enthalpy change (ΔH): -92 kJ Read More …

calculations

Entropy

May 7, 2014March 11, 2021 Surfguppy1 CommentThermodynamics
What is entropy?

What is entropy? Entropy refers to the amount of unusable energy in a system. When water flows over a dam, it loses some of its useful energy as heat Solid wood burns to become ash and releases gases. Solid ice Read More …

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