|Enthalpy||Entropy||Gibbs Free Energy|
|Enthalpy is the amount of heat energy transferred (heat absorbed or emitted) in a chemical process under constant pressure.||Entropy measures the amount of heat dispersed or transferred during a chemical process.||Gibbs Energy is also known as energy available to initiate a chemical process under constant pressure and temperature.|
|It is expressed as a change in enthalpy (ΔH) because the total enthalpy (H) of a system cannot be measured directly.||Nature tends to form chaos than order — aging, decaying, rusting, etc. Usable energy is transformed to unusable energy when work is performed. Entropy is often described as a measure of randomness but this mustn’t be confused with random patterns or arrangements.Entropy is about heat. The change in entropy is expressed as ∆S. The higher energy dispersal means higher entropy.||Some reactions are spontaneous (eg. rusting). A spontaneous process happens by itself without any energy added to the system (apart from the activation energy). A non-spontaneous process will not take place unless it is driven by an external source of energy.
∆G = ∆H — T•∆S
∆G = Gibbs Free Energy
∆H = Change in Enthalpy
T = Temperature in K
∆S = Change in Entropy
|ΔH < 0||∆S > 0||∆G < 0
|• Total energy of products lower than total energy of reactants.
• The process is exothermic.
• Gives off heat.
|Entropy increases.||Process is spontaneous|