Enthalpy

WHAT IS ENTHALPY CHANGE?

anthalpy_change_diagram

deltaH - enthalpy change diagram

Don’t get hung up with the term enthalpy change. It is just a simple term to denote the amount of heat that passes in or out of a system during a chemical reaction under constant pressure.

Watch a 50 seconds movie about enthalpy change

deltaH - enthalpy change diagram
Don’t get too worried about the term “constant pressure” either. However, it is important to know that enthalpy change refers to reactions carried out under constant pressure only. In school, you can measure the heat exchange of a reaction in a device called calorimeter. The experiment is conducted under atmospheric pressure which is constant. By measuring the temperature rise or drop for the reaction, you can determine the heat exchange — or the enthalpy change. It isn’t the most accurate way of determining enthalpy change because of heat losses but at least the experiment can be conducted easily and safely by following safety procedures.

Enthalpy change is expressed as

ΔH = kJ/mol-rxn

kJ = kiloJoules
mol = moles
rxn = reaction

A calorimeter

a calorimeter diagram

Calorimeters come in many shapes and sizes. The above shows an example of an experiment measuring enthalpy change in burning a food substance (eg. a peanut). In the real world, you may not go about measuring heat change in processes around you (e.g. a marshmallow undergoing oxidation), but enthalpy change happens frequently and all the time in nature.

Enthalpy change is the name given to the amount of heat given out or absorbed in a chemical reaction.

  • If enthalpy change is -‘ve, reaction is exothermic — giving off heat.
  • If enthalpy change is +’ve, reaction is endothermic — absorbing heat.

enthalpychange-diagram

Example of Endothermic Reactions

photosynthesis endothermic reaction

Photosynthesis absorbs heat

Sunlight + 6CO2(g) + 6H2O(l) = C6H12O6(aq) + 6O2(g)

  • Photosynthesis absorbs heat to create glucose (C6H12O6)
  • The glucose produced has higher energy than the sunlight, water and carbon dioxide that it absorbs
  • Therefore the reaction is endothermic, heat absorbing, and the enthalpy change is positive.

youtube-344106__180Watch an effective endothermic reaction experiment by Professor Bob Burk — http://www.youtube.com/watch?v=5RJLvQXce4A#t=27

Example of Exothermic Reactions

Sodium and chlorine exothermic reation

Sodium and chloride combines to become sodium chloride (table salt)

Na(s) + 0.5Cl2(s) = NaCl(s)

  • During this process, heat is given out
  • The energy of the product (NaCl) has lower energy than the reactants (Na + Cl).
  • Therefore the enthalpy change is negative

Example Calculation

Example of enthalpy change calculation of propane combustion icon-sg50

Leave a Reply

Your email address will not be published.